Combine the starter, milk and flour in a large mixing bowl
Cover and rest at room temperature for 2-3 hours
Preheat the oven to 175ºC/350°F/Gas mark 4
Lightly grease a 23 x 33cm (9 x 13-inch) cake tin
In a separate bowl, beat together the sugar, oil, vanilla, salt, baking soda, cocoa and espresso powder - the mixture will be grainy
Add the eggs one at a time, beating well after each addition
Gently combine the chocolate mixture with the starter/flour/milk mixture, stirring until smooth. It will be gloopy at first; however, the batter will become smoother as you continue to beat gently
Pour the batter into the prepared cake tin
Bake for 30-40 minutes or until a skewer inserted into the middle comes away clean
Remove the cake from the oven and set it on a wire rack to cool while you make the icing
For the icing
Sift the icing sugar into a large mixing bowl. Set it aside
In a small saucepan set over medium heat, melt the butter and add the buttermilk/yoghurt
Dissolve the espresso powder in the hot water, add to the pan, and bring the mixture just to a boil
Immediately pour the simmering liquid over the icing sugar in the bowl, and beat until smooth
Pour the warm icing over the cake. If you wait too long and the icing stiffens up, just spread it over the cake with an offset spatula
For the drizzle
Combine the chocolate pieces, milk and golden syrup in a microwave-safe container. Microwave until the chocolate softens, then stir until smooth (a couple of 10-second bursts)